ÜberN-Methyl-α-acetyl-indol

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Methyl 3-(1H-indol-3-yl)propano­ate

The mol-ecule of the title compound, C(12)H(13)NO(2), adopts an essentially planar conformation (r.m.s. deviation = 0.057 Å). In the crystal, the mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, generating chains along [201].

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Conformational properties of N-acetyl-N-methyl-α,β-dehydroalanine N’-methylamide*

The conformational properties of Ac-∆(Me)Ala-NHMe (N-acetyl-N-methyl-α,β-dehydroalanine N’methylamide), as the simplest model of N-methyl-α,β-dehydroamino acids, was examined with theoretical methods and in comparison with Ac-∆Ala-NHMe and Ac-∆Ala-NMe2. The N-terminal amide of the ∆(Me)Ala residue easily adopts the configuration cis and the torsion angles φ, ψ are highly flexible. The ∆(Me)Ala ...

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Benzyl N′-(1-methyl-1H-indol-2-ylmethyl­ene)hydrazinecarbodithio­ate

In the title compound, C(18)H(17)N(3)S(2), the dihedral angle between the planes of the aromatic ring systems is 83.63 (16)°. In the crystal structure, inversion dimers occur, linked by pairs of N-H⋯S hydrogen bonds.

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Benzyl N′-(1-methyl-1H-indol-3-yl­methyl­idene)hydrazinecarbodithio­ate

The N'-(1-methyl-1H-indol-3-ylmethyl-idene)hydrazine-carbo-dithio-ate portion of the title mol-ecule, C(18)H(17)N(3)S(2), is nearly planar; this unit and the phenyl ring subtend an angle of 112.9 (2)° at the methyl-ene C atom.

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In the title compound, C(11)H(10)N(2), the carbonitrile group is twisted away from the indole plane [C(cy)-C(me)-C(ar)-C(ar) = 66.6 (2)°; cy = cyanide, me = methyl-ene and ar = aromatic]. In the crystal, N-H⋯N hydrogen bonds link the mol-ecules into C(7) chains propagating in the [001] direction.

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ژورنال

عنوان ژورنال: Berichte der deutschen chemischen Gesellschaft

سال: 1914

ISSN: 0365-9496,1099-0682

DOI: 10.1002/cber.19140470144